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Inorganic chemistry in aqueous solution / Jack Barrett

By: Material type: TextPublication details: Royal Society of Chemistry, London : 2003Description: vii, 184 pISBN:
  • 9780854044719
Subject(s): DDC classification:
  • 546 B2741
Contents:
1. WATER AND ITS SOLVENT PROPERTIES. Introduction -- Liquid water -- 2. LIQUID WATER AND THE HYDRATION OF IONS. The structure of liquid water -- Ions and their hydration -- Gibbs energies and enthalpies of formation of hydrated ions -- Standard molar enthalpies of hydration of ions -- The absolute value for the standard molar enthalpy of hydration of the proton -- Absolute values of the standard molar enthalpies of hydration of ions -- Standard molar entropies of hydration of ions -- 3. ACIDS AND BASES; FORMS OF IONS IN AQUEOUS SOLUTION; ION HYDROLYSIS & COMPOUND SOLUBILITY. Acids and bases in aqueous solutions -- Brønsted and Lowry acids and bases -- pH and the pH scale -- Factors influencing acidic and basic behaviour in aqueous solutions -- Forms of ions in aqueous solution; hydrolysis -- Solubilities of ionic compounds in water -- 4. THERMODYNAMICS AND ELECTRODE POTENTIALS. Changes in standard Gibbs energy and their relation to standard electrode potentials -- The hydrated electron and absolute values of reduction potentials -- 5. THE STABILITIES OF IONS IN AQUEOUS SOLUTION. The limits of stability of ions in aqueous systems -- Latimer and Volt-equivalent (Frost) diagrams -- 6. PERIODICITY OF AQUEOUS CHEMISTRY I: S- AND P-BLOCK CHEMISTRY. Periodicity of the ions formed by the s- and p-block elements -- The detailed aqueous chemistry of the s- and p-block elements -- Summary of the s- and p-block periodicity -- 7. PERIODICITY OF AQUEOUS CHEMISTRY II: D-BLOCK CHEMISTRY. The ions formed by the transition elements -- Enthalpies of hydration of some transition element cations -- Variations in the enthalpies of hydration of the +2 and +3 ions of the transition elements -- Variations of ionic forms and redox behaviour across the first series of transition elements -- General redox chemistry of the d-block elements -- 8. PERIODICITY OF AQUEOUS CHEMISTRY III: F-BLOCK CHEMISTRY. The lanthanides -- The actinides -- Answers to problems -- Subject index.
List(s) this item appears in: Chemistry
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Books UE-Central Library 546 B2741 (Browse shelf) Available T221D

includes index

1. WATER AND ITS SOLVENT PROPERTIES. Introduction --
Liquid water --
2. LIQUID WATER AND THE HYDRATION OF IONS. The structure of liquid water --
Ions and their hydration --
Gibbs energies and enthalpies of formation of hydrated ions --
Standard molar enthalpies of hydration of ions --
The absolute value for the standard molar enthalpy of hydration of the proton --
Absolute values of the standard molar enthalpies of hydration of ions --
Standard molar entropies of hydration of ions --
3. ACIDS AND BASES; FORMS OF IONS IN AQUEOUS SOLUTION; ION HYDROLYSIS & COMPOUND SOLUBILITY. Acids and bases in aqueous solutions --
Brønsted and Lowry acids and bases --
pH and the pH scale --
Factors influencing acidic and basic behaviour in aqueous solutions --
Forms of ions in aqueous solution; hydrolysis --
Solubilities of ionic compounds in water --
4. THERMODYNAMICS AND ELECTRODE POTENTIALS. Changes in standard Gibbs energy and their relation to standard electrode potentials --
The hydrated electron and absolute values of reduction potentials --
5. THE STABILITIES OF IONS IN AQUEOUS SOLUTION. The limits of stability of ions in aqueous systems --
Latimer and Volt-equivalent (Frost) diagrams --
6. PERIODICITY OF AQUEOUS CHEMISTRY I: S- AND P-BLOCK CHEMISTRY. Periodicity of the ions formed by the s- and p-block elements --
The detailed aqueous chemistry of the s- and p-block elements --
Summary of the s- and p-block periodicity --
7. PERIODICITY OF AQUEOUS CHEMISTRY II: D-BLOCK CHEMISTRY. The ions formed by the transition elements --
Enthalpies of hydration of some transition element cations --
Variations in the enthalpies of hydration of the +2 and +3 ions of the transition elements --
Variations of ionic forms and redox behaviour across the first series of transition elements --
General redox chemistry of the d-block elements --
8. PERIODICITY OF AQUEOUS CHEMISTRY III: F-BLOCK CHEMISTRY. The lanthanides --
The actinides --
Answers to problems --
Subject index.

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