TY - BOOK AU - Moss,Robert A. AU - Platz,Matthew AU - Jones,Maitland TI - Reactive intermediate chemistry / SN - 3790391233244 (hbk) U1 - 541.394 22 PY - 2004/// CY - Hoboken, N.J. PB - Wiley-Interscience KW - Chemical reaction, Conditions and laws of KW - Intermediates (Chemistry) KW - Organic reaction mechanisms N1 - Includes bibliographical references and index; Contents Preface Part 1: reactive intermediates 1.carbocations 00 r.a. Mcclelland 2.crossing the borderline between sn1 and sn2 nucleophilic substitution at Aliphatic carbon 00 t.l. Amyes, m.m. Toteva, and j.p. Richard 3.carbanions S. Gronert 4.radicals m. Newcomb 5.non-kekul molecules as reactive intermediates 00 J.a. Berson 6.organic radical ions 00 H.d. Roth 7.singlet carbenes 00 m. Jones, jr., and r.a. Moss 8.stable singlet carbenes 00 G. Bertrand 9.triplet carbenes 00 h. Tomioka 10.atomic carbon 00 P.b. Shevlin 11.nitrenes 00 M.s. Platz 12.synthetic carbene and nitrene chemistry 00 M.p. Doyle 13.nitrenium ions 00 D.e. Falvey 14.* silylenes 00 W. Ando, and n. Tokitoh 15.strained hydrocarbons: structures, stability, and reactivity 00 K.b. Wiberg 16.arynes 00 M. Winkler, h.h. Wenk, and w. Sander Part 2: methods and temporal regimes 17.matrix isolation 00 T. Bally 18.nanosecond laser flash photolysis: a tool for physical organic chemistry 00 J.c. Scaiano 19.*the picosecond realm E. Hilinski 20.reactions on the femtosecond time scale 00 j.e. Baldwin 21.potential energy surfaces and reaction dynamics 00 B.k. Carpenter 22.the partnership between electronic structure calculations and experiments in the Study of reactive intermediates 00 W.t. Borden ER -